Selectivated ZSM-035 catalyst and process for selectively converting ethene to linear butenes therewith

阅读量:

39

申请(专利)号:

US08/228770

申请日期:

19940418

公开/公告号:

US05449849A

公开/公告日期:

19950912

申请(专利权)人:

MOBIL OIL CORPORATION

发明人:

FT DiguiseppiS HanRH Heck

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被引量:

13.2万

摘要:

The present invention relates to a catalyst and its use in a process for the conversion of ethene to a product rich in linear butenes, especially 2-butene, comprising contacting a feedstock comprising ethene under dimerization conditions with a catalyst composition comprising a porous crystalline silicate having the structure of ZSM-35 which has been treated by a) fluoriding, e.g., with NH.sub.4 F, and then b) at least partially surface deactivated for acid catalyzed reactions by chemisorption of a surface-deactivating agent which possesses an average cross section diameter greater than that of the zeolite pores, e.g., collidine.

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2012
被引量:7734

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