Reactions of cyclic oxalyl compounds, part 29: A simple synthesis of functionalized 1H-pyrimidines
摘要:
4-Benzoyl-5-phenylfuran-2,3-dione ( 1 ) and the semicarbazones 2 , ureas and thioureas 6 , respectively, combine with loss of water and carbondioxide yielding the 1 H -pyrimidine derivatives 3 and 7 , respectively, in moderate yields (30–75%). Hydrolysis of 3 b leads to the 1-amino-pyrimidine-2-one 4 .
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关键词:
5-Benzoyl-1-methyleneamino-4-phenyl-1H-pyrimidine-2-ones 1-Alkyl-5-benzoyl-4-phenyl-1H-pyrimidine-2-ones 1,4,5-Substituted pyrimidine-2-thiones Cyclocondensation reactions
DOI:
10.1007/BF00808773
被引量:
年份:
1989
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