Clean chemical synthesis of 2-amino-chromenes in water catalyzed by nanostructured diphosphate Na2CaP2O7

阅读量:

34

作者:

A SolhyA ElmakssoudiR TahirM KarkouriM Zahouily

展开

摘要:

A versatile, alternative and environmentally benign three-component strategy to the synthesis of a series of 2-amino-chromenes has been successfully performed in water, using nanostructured diphosphate Na2CaP2O7(DIPH) as a basic catalyst. The products are obtained in high recoveries from the one-pot multi-component reaction procedure involving carbonyl compounds, malononitrile and 1-naphtol, resulting in a green synthetic protocol with high atom economy. The catalyst is waste-free, easily prepared, and efficiently re-used. The prepared 2-amino-chromenes, in presence of acetic anhydride, have been easily converted to benzo(a)anthracene derivatives.

展开

DOI:

10.1002/chin.201117144

被引量:

50

年份:

2011

通过文献互助平台发起求助,成功后即可免费获取论文全文。

相似文献

参考文献

引证文献

来源期刊

Cheminform
2011/04/26

引用走势

2012
被引量:15

辅助模式

0

引用

文献可以批量引用啦~
欢迎点我试用!

引用