Photoisomerizable Heterodienes Derived from a Phosphine Borane

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阅读量:

78

摘要:

Stable relations: Reaction of phenylazide with a phosphine borane derivative gives rise to an intramolecularly stabilized phosphazide 1 (R=iPr, R′=mesityl) that undergoes an unprecedented photoisomerization process associated with a change from an N→B to an Nβ→B interaction (see scheme). The generality and possible reversibility of such phenomena are demonstrated with the related phosphazine adduct 2.

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DOI:

10.1002/anie.200605078

被引量:

191

年份:

2007

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2010
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