Photoisomerizable Heterodienes Derived from a Phosphine Borane
摘要：
Stable relations: Reaction of phenylazide with a phosphine borane derivative gives rise to an intramolecularly stabilized phosphazide 1 (R=iPr, R′=mesityl) that undergoes an unprecedented photoisomerization process associated with a change from an N→B to an Nβ→B interaction (see scheme). The generality and possible reversibility of such phenomena are demonstrated with the related phosphazine adduct 2.
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DOI：
10.1002/anie.200605078
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年份：
2007
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来源期刊
Angewandte Chemie International Edition
2007年04月27日
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2010
被引量：35
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