Catalytic Cyanosilylation of Ketones Using Organic Catalyst 1,1,3,3-Tetramethylguanidine
摘要：
1,1,3,3-Tetramethylguanidine acts as a highly effective catalyst for cyanosilylation of various ketones and aldehydes to the corresponding cyanohydrin trimethylsilyl ethers in up to 99% yield. The reaction proceeds smoothly with 0.1 mol % catalyst loading at 25 °C under solvent-free conditions.
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关键词：
cyanation, nitrile formation hydrosilylation, silylation, phosphorylation nitriles (acyclic compounds nitriles (benzene compounds
DOI：
10.1016/j.tetlet.2005.12.135
被引量：
年份：
2006
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来源期刊
ChemInform
2006/03/01
引用走势
2007
被引量：28
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