6-Substituted Indanoyl Isoleucine Conjugates Mimic the Biological Activity of Coronatine
摘要：
The 6-substituted indanoyl isoleucine conjugates of type 12 are potent elicitors of plant secondary metabolism and tendril coiling. The 6-substituted indanoyl carboxylic acid is available in four steps from 1,2,3,4-tetrahydronaphthalene (6). Key steps of the synthesis involve double acylation of 6 followed by oxidative cleavage and intramolecular Friedel-Crafts acylation of the resulting dicarboxylic acid 10. The conjugate with isoleucine (12) triggers volatile biosynthesis in the Lima bean at 10μm and coiling of the touch-sensitive tendrils of Bryonia dioica at 20μm.
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DOI：
10.1002/1099-0690(200105)2001:9<1663::AID-EJOC1663>3.0.CO;2-I
被引量：
年份：
2010
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