Semiclassical Transition Probabilities (S Matrix) of Vibrational—Translational Energy Transfer
摘要：
Uniformized coordinates and an integral expression for the semiclassicalSmatrix, derived elsewhere, are described and applied to vibrational transition probabilities. The expression obeys microscopic reversibility. The numerical results are compared with the exact quantum mechanical results of Secrest and Johnson.
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关键词：
n32240* --physics--atomic & molecular physics--collision phenomena atoms energy energy levels inelastic scattering molecules s- matrix transients vibrational state collision processes/s matrix for vibrational-- translational energy transfer in atomic and molecular
DOI：
10.1063/1.1675736
被引量：
年份：
1971
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