摘要：

Details research that linked further units onto the inner surface of ring-shaped clusters of mixed-valence polyoxomolybdate molecules which would not be stable in isolation. Applications of polyoxometalate chemistry; Constitution of such molecules; How they are formed; The intermediate Mo176 form with Mo36 additions to either side of the ring; Formulas; Implications of understanding the stepwise growth process; Methods, physical data, and X-ray structure analysis.

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