Mechanistic studies on ruthenium-catalyzed hydrogen transfer reactions
摘要：
Ruthenium-catalyzed hydrogen transfer from (S)-α-deuterio-α-phenylethanol [(S)-1] to acetophenone with catalyst 3 occurs with retention of deuterium at the α-carbon of the alcohol product whereas H/D scrambling occurs with catalyst 2.
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关键词：
mechanistic studies catalysis ruthenium hydrogen transfer racemization transfer hydrogenation alcohols ketones amines imines
DOI：
10.1039/b000530o
被引量：
年份：
2000
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