Investigation of multiplet splitting of Fe 2p XPS spectra and bonding in iron compounds

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2728

作者：

AP Grosvenor，BA Kobe，MC Biesinger，NS Mcintyre

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摘要：

Ferrous (Fe 2+ ) and ferric (Fe 3+ ) compounds were investigated by XPS to determine the usefulness of calculated multiplet peaks to fit high-resolution iron 2p 3/2 spectra from high-spin compounds. The multiplets were found to fit most spectra well, particularly when contributions attributed to surface peaks and shake-up satellites were included. This information was useful for fitting of the complex Fe 2p 3/2 spectra for Fe 3 O 4 where both Fe 2+ and Fe 3+ species are present. It was found that as the ionic bond character of the iron —ligand bond increased, the binding energy associated with either the ferrous or ferric 2p 3/2 photoelectron peak also increased. This was determined to be due to the decrease in shielding of the iron cation by the more increasingly electronegative ligands. It was also observed that the difference in energy between a high-spin iron 2p 3/2 peak and its corresponding shake-up satellite peak increased as the electronegativity of the ligand increased. The extrinsic loss spectra for ion oxides are also reported; these are as characteristic of each species as are the photoelectron peaks. Copyright 2004 John Wiley & Sons, Ltd.

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关键词：

Experimental/ binding energy bonds (chemical) electronegativity iron compounds surface chemistry X-ray photoelectron spectra/ multiplet splitting XPS spectra bonding iron compounds Fe 2+ Fe 3+ ferrous compounds ferric compounds shake-up satellites ionic bond character iron-ligand bond binding energy electronegative ligands extrinsic loss spectra Fe 3O 4/ A8280P Electron spectroscopy for chemical analysis (photoelectron, Auger spectroscopy, etc.) A8265 Surface chemistry/ Fe3O4/bin Fe3/bin Fe/bin O4/bin O/bin