Asymmetric transformations catalyzed by enzymes in organic solvents

A program REDOX was worked out for spectrophotometric characteristics of redox equilibria in the solution. The program allows indirect logarithmic analysi...

Klibanov，M Alexander - 《Accounts of Chemical Research》

ChemInform Abstract: Tributylphosphine: A Remarkable Acylation Catalyst.

ChemInform is a weekly ing Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform ...

E.，VEDEJS，S.，... - 《Cheminform》

New chiral phospholanes; Synthesis, characterization, and use in asymmetric hydrogenation reactions

We describe the practical synthesis of enantiomerically pure trans-2,5-disubstituted-1-phenylphospholanes which are then employed in the preparation of a n...

Mark，J.，Burk，... - 《Tetrahedron Asymmetry》

Diastereoselective aldol reactions of β-silyloxy ethyl ketones. Application to the total synthesis of bafilomycin A1

Studies directed toward the C17C18 aldol bond construction in the macrolide antibiotic bafilomycin A1 are described. The effect of the β-substituent in the aldol reactions of α-unsubstituted enolates is documented for various model c...

David，A.，Evans，... - 《Tetrahedron Letters》

Enzymic preparation of enantiomerically pure cyclohexanols: ester synthesis by irreversible acyl transfer

Enantiomerically pure cyclohexanols are prepared enzymically via irreversible acyl transfer; they are valuable substitutes for 8-phenylmenthols and are pot...

K Laumen，R Seemayer，MP Schneider - 《Journal of the Chemical Society Chemical Communications》

Tributylphosphine-catalyzed acylations of alcohols: Scope and related reactions

(2R,4R,5S)-2-Amino-4,5-(1,2-cyclohexyl)-7-phosphonoheptanoic acid (15) has been prepared by an efficient nine-step route (16% overall yield) which uses che...

E Vedejs，NS Bennett，LM Conn，... - 《Journal of Organic Chemistry》

Resolution of Enantiomers via Biocatalysis

This chapter contains sections titled

C Sih，S Wu - 《Topics in Stereochemistry》

Kinetic and thermodynamic atropdiastereoselection in the synthesis of the M(5–7) tripeptide portion of vancomycin

The C α stereochemistry of the position-5 arylglycine plays a pivotal role in determining the kinetic atropdiastereoselection in the oxidative biaryl cyc...

DA Evans，CJ Dinsmore - 《Tetrahedron Letters》

Tributylphosphine: a remarkable acylation catalyst

ChemInform is a weeklying Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInformof ...

E Vedejs，ST Diver - 《Cheminform》

ChemInform Abstract: New Chiral Phospholanes; Synthesis, Characterization, and Use in Asymmetric Hydrogenation Reactions.

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a Chem...

MJ Burk，JE Feaster，RL Harlow - 《Cheminform》