Enzymatic esterification of 3-hydroxybutyric acid
摘要:
Candida cylindracea lipase catalysed esterification of (±)-3-hydroxybutyric acid (1) with n-butanol was studied in different solvents. This provided an alternative preparative method for the versatile chiron. butyl ( S )-3-hydroxybutyrate (2) via kinetic resolution of (±)-1 With toluene as the reaction medium, the enantioselection was found to be excellent for 2 and moderate for the resolved acid (1).
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DOI:
10.1007/BF00128313
被引量:
年份:
1993
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