Applied hydroformylation.
摘要：
Special reviews were dedicated to spectroscopic aspects of catalysts and catalytic intermediates. In 2008, Haumann and Riisager summarized recent developments in the area of hydroformylation in room-temperature ionic liquids (RTIL). Especially the production of high-boiling aldehydes or alcohols from long-chain and branched olefins remains a domain of cobalt catalysis. There are still some patent activities in this area from Shell, which indicates a renewed interest. One of the main differences between all of these large-scale rhodium-catalyzed hydroformylations is the technology used to separate the product and the catalyst with the aim of reusing the metal. The lifetime of a catalyst charge may exceed 1 year under the condition that sufficient purity of the feed and careful process control is guaranteed.
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DOI：
10.1021/cr3001803
被引量：
年份：
2012
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