Polyketide Assembly by Alkene–Alkyne Reductive Cross-Coupling: Spiroketals Through the Union of Homoallylic Alcohols
摘要：
A reaction sequence involving regioselective formal hydroalkynylation, reductive ene-yne cross-coupling, and oxidative cyclization is developed to prepare stereochemically dense spiroketals following similar pathways.
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关键词：
pyran derivatives spirocyclic compounds C-C bond formation ring closure reactions diastereoselective syntheses, enantioselective syntheses (incl. cis/trans-isomerism)
DOI：
10.1002/chin.201041122
被引量：
年份：
2010
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