Chiral organometallic half-sandwich complexes with defined metal configuration.

Chiral organometallic half-sandwich complexes with stereogenic metal atoms are close relatives of chiral organic compounds with stereogenic carbon atoms. S...

C Ganter - 《Cheminform》

Synthesis, Structures, and Reactivities of Rhodium and Ruthenium Complexes with a Novel Chiral CyclopentadienylFerrocenyldiphenylphosphine Bidentate Ligand

Novel rhodium(I) and ruthenium(II) complexes with the chiral cyclopentadienylphosphine bidentate ligand PPFCp have been prepared and characterized crystall...

Y Nishibayashi，I Takei，M Hidai - 《Organometallics》

The chemistry of chiral heterometallocenes

Chiral heterometallocene derivatives, namely phospha- and azaferrocenes, have recently attracted considerable interest with regard to their stereochemical ...

Ganter，Christian - 《Journal of the Chemical Society Dalton Transactions》

ChemInform Abstract: A Chiral Sulfoxide-Ligated Ruthenium Complex for Asymmetric Catalysis: Enantio- and Regioselective Allylic Substitution.

This reaction proceeds with good regio- and enantioselectivity yielding preferably the branched products.

BM Trost，M Rao，AP Dieskau - 《Cheminform》

The grinding of titanium alloys: C. T. Yang and M. C. Shaw. ASME, transactions, v. 77, July 1955, p. 645–660

Estrogen 2,3- and 3,4-quinones are reactive species toward nucleophiles and Michael acceptors. As such, they can bind to DNA and induce cellular damages. A...

Robert S Paley - 《Chemical Reviews》

Synthesis of a new iron Lewis acid catalyst possessing a chelating cyclopentadienyldiphenylphosphinite ligand, (5:1-C5H4CH(Ph)OPPh2)

Estrogen 2,3- and 3,4-quinones are reactive species toward nucleophiles and Michael acceptors. As such, they can bind to DNA and induce cellular damages. A...

Mayer，M.，F.，... - 《Journal of Organometallic Chemistry》

Chiral organometallic half-sandwich complexes with defined metal configuration

Chiral organometallic half-sandwich complexes with stereogenic metal atoms are close relatives of chiral organic compounds with stereogenic carbon atoms. Similarities and differences between these two classes of compounds are outlined. S...

C Ganter - 《Chemical Society Reviews》

ChemInform Abstract: Cyclopentadienylmetal Complexes Bearing Pendant Phosphorus, Arsenic, and Sulfur Ligands

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a Chem...

Holger，Butenschoen - 《Cheminform》

Synthesis of ruthenium complexes with planar-chiral cyclopentadienyl-pyridine or -phosphine bidentate ligands

Novel ruthenium complexes possessing planar-chiral cyclopentadienyl-pyridine or -phosphine bidentate ligands have been synthesized from (trisubstituted cyc...

N Dodo，Y Matsushima，M Uno，... - 《Journal of the Chemical Society Dalton Transactions》

Stereospecific CO Insertion into the RhodiumMethyl σ Bond in [(Cp'-P)Rh(CO)(Me)]BF 4 and Deinsertion from [(Cp'-P)Rh(COMe)I]: Experimental Evidence for Methyl Migration

We have shown concrete evidence for migration of an alkyl group in carbonyl insertion and deinsertion steps between the methyl carbonyl rhodium complex [{η5:η1-(Ind-P)n=3}Rh(CO)Me]BF4 (3) and the acetyl rhodium complex {η5:η1-(Ind-P)...

Y Kataoka，A Shibahara，T Yamagata，... - 《Organometallics》