Interaction of orbitals through space and through bonds

来自 ACS

阅读量:

154

作者:

R Hoffmann

展开

摘要:

This paper has been concerned with a necessary addendum to the chemist's view of a molecule. Localized orbitals or groups of orbitals may interact with each other directly, through space, or indirectly, through other bonds in the molecule. The latter interaction may operate over surprisingly long distances. The primary effects of such interaction and their most direct measure are through ionization potentials and electronic spectra. Stability and reactivity are affected as well. The analysis of these interactions is most conveniently made through the language of perturbation theory; here, as everywhere, the role of symmetry is paramount.

展开

DOI:

10.1021/ar50037a001

被引量:

1925

年份:

1971

通过文献互助平台发起求助,成功后即可免费获取论文全文。

相似文献

参考文献

引证文献

来源期刊

引用走势

2010
被引量:131

辅助模式

0

引用

文献可以批量引用啦~
欢迎点我试用!

引用