Palladium(II)-catalyzed carboxylation of benzene and other aromatic compounds with carbon monoxide under very mild conditions
摘要:
Aromatic compounds such as benzene, toluene, chlorobenzene, anisole, and naphthalene were carboxylated by palladium(II) acetate catalyst with carbon monoxide in the presence of potassium peroxodisulfate in trifluoroacetic acid (TFA) at room temperature under atmospheric pressure. The aromatic carboxylic acids were formed in good yields; for example, the carboxylation of benzene with carbon monoxide proceeds quantitatively under the optimal conditions.
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DOI:
10.1016/S0022-328X(98)01160-7
被引量:
年份:
1999
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