A Cationic High‐Valent Cp*CoIII Complex for the Catalytic Generation of Nucleophilic Organometallic Species: Directed CH Bond Activation
摘要：
Active without activation: In an inexpensive and atom-economical approach to CH bond functionalization, a cationic CoIII complex (see scheme) was used to generate nucleophilic organometallic species in situ without additional activating reagents. Under these conditions, aryl CH bonds underwent efficient addition to polar electrophiles, including ,β-unsaturated N-acyl pyrroles as β-substituted ester and amide surrogates.
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DOI：
10.1002/anie.201209226
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年份：
2013
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来源期刊
Angew Chem Int Ed Engl
2013/3/27 0:00:00
引用走势
2015
被引量：124
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