Enantioselective oxidation of (±)-2-phenyl-1-propanol to ( S )-2-phenyl-1-propionic acid with Acetobacter aceti : influence of medium engineering and immobilization
摘要：
The enantioselective oxidation of ( RS )-2-phenyl-1-propanol to ( S )-2-phenylpropionic acid catalysed by Acetobacter aceti occurred under very mild conditions. The rate, substrate tolerance and enantioselectivity (enantiomeric ratio, E >200) can be increased dramatically simply by adding cyclodextrins to the reaction medium. Cells immobilized in calcium alginate showed good operational stability and good enantioselectivity (e.e. 94%); the catalyst can be re-used at least five times without e.e. diminution.
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DOI：
10.1016/S0957-4166(02)00641-9
被引量：
年份：
2002
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