Activation and amplification of the third-order NLO and luminescent responses of a precursor cluster by a supramolecular approach
摘要:
Solvothermal reactions of [Et4N][Tp*WS3(CuCl)3] (1) (Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate) with CuCN and KCu(CN)2afforded two [Tp*WS3Cu3]-based coordination polymers [Tp*WS3Cu3(μ3-DMF){Cu(CN)3}]2(2) and K[Tp*WS3Cu3(μ3-DMF){Cu2(CN)4.5}]2(3). The third-order NLO and PL responses of1were activated and greatly amplified through its assemblyviathe [Cu(CN)3]2and [Cu4(CN)9]5species in2and3.
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DOI:
10.1039/c2cc30581j
被引量:
年份:
2012
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来源期刊
Chemical Communications
20120409
引用走势
2015
被引量:14
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