Palladium(O)-catalyzed substitution of allylic substrates in an aqueous-organic medium

阅读量:

24

作者:

ErrolBlartandJeanPierreGeneˆtandMohamedSafiand

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摘要:

A palladium(O)-water soluble catalyst prepared in situ from palladium acetate and the sulfonated triphenyl phosphine P(C6H4-m-SO3Na)3 (or tppts) is an efficient catalyst for allylic substitution with various carbon and heteronucleophiles in an aqueous-organic medium, allowing a very easy separation of the product(s) and the recycling of the catalyst.

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DOI:

10.1016/S0040-4020(01)80772-9

被引量:

189

年份:

1994

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来源期刊

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2010
被引量:23

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