Iridium and rhodium complexes bearing a silyl-bipyridine pincer ligand: synthesis, structures and catalytic activity for C-H borylation of arenes
摘要：
Unsaturated 16-electron iridium and rhodium complexes bearing a silyl-bipyridine-based SiNN-pincer ligand (BpySiNN) were synthesised and characterised by X-ray crystallography and NMR spectroscopy. The iridium-BpySiNN complex facilitated the catalytic C(sp2)鈥揌 borylation of arenes to give arylboronate esters in high yields (鈮) under mild conditions (鈭掳C).
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关键词：
TRANSITION-METAL-COMPLEXES RUTHENIUM(II) COMPLEX STABILIZED FORM XANTSIL ACTIVATION IR (9 9-DIMETHYLXANTHENE-4 5-DIYL)BIS(DIMETHYLSILYL) HETEROARENES SENSITIVITY SELECTIVITY
DOI：
10.1039/d2dt01227h
年份：
2022
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