Synthesis of verdinochlorins: A new class of long-wavelength absorbing photosensitizers
摘要：
Reaction of 132-oxopyropheophorbide a with CH2N2 produced three isomeric methoxyverdinochlorins via expansion of the cyclopentanedione ring E; these long-wavelength absorbing verdinochlorins represent the first example of verdins with a reduced pyrrolic ring system, and their structural assignments have been made on the basis of 1H NMR studies; a mechanism of verdinochlorin formation is discussed.
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DOI：
10.1039/A801367E
年份：
1998
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