Reactions of CS2 with metal cluster carbonyls of the iron triad; synthesis and X-ray structure of [Fe4(CO)12(CS)S]
摘要：
Reaction of [Fe3(CO)12] with CS2 in hexane, at 80 °C, under moderate CO/Ar pressure gives, as one of the main products, [Fe4(CO)12(CS)S], which has been shown by a single crystal X-ray analysis to contain a thiocarbonyl ligand co-ordinated to the cluster in a novel bonding mode.
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DOI：
10.1016/S0022-328X(00)86674-7
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年份：
1980
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来源期刊
Journal of Organometallic Chemistry
1980/01/01
引用走势
1985
被引量：6
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