摘要：

Organic synthesis is essential to creating new materials. While synthetic design has reached a high level of sophistication, many details remain unplannable. To become proficient in organic synthesis, one must study case histories in the same way as a lawyer does. Attention must be paid to overcoming stumbling blocks as one prepares himself to meet future challenges of similar kinds. This book discusses many important syntheses, with emphasis on the need for detours and ways leading back to the main pathways. It thus focuses on one of the most important aspects of organic synthesis, which virtually none of the synoptic literature addresses. Sample Chapter(s) Chapter 1: Chemoselectivity Problems: (9,588 KB) Request Inspection Copy Contents: Chemoselectivity Problems: Longifolene Eremophilone Cocaine Sinularene (-)-Calicheamicinone Perforenone δ-Coniceine Longipinenes Trichodiene (+)-Gracillin-B and (+)-Gracillin-C Panasinsenes (-)-Bertyadionol Vitamin-B12 Cedrol Copaenes and Ylangenes Equilin β-Cuparenone Cyperolone Estrone Lycoramine Reserpine 6a-Epipretazettine Antheridic Acid Brefeldin-A 7,20-Diisocyanoadociane Dehydroabietic Acid and Deoxypodocarpic Acid Terramycin Isocomene Longifolene Ibogamine Camptothecin Methyl Homodaphniphyllate Spiniferin-1 Fukinone Colchicine Lycopodine Cinchona Alkaloids Compactin Pleuromutilin Lobophytum Cembranolide-I Modhephene Triquinane Sesquiterpenes: Silphinene, Hirsutene, and Δ9(12)-Capnellene O-Methylpallidinine α-Bourbonene Dendrobine Stereochemical Problems: Porantherine Isocomene Aphidicolin Aromaticin and Aromatin Conessine Nootkatone Stemodin and Maritimol Gibberellic Acid Reserpine Huperzine-A Dihydrocorynantheine Geissoschizine and Geissoschizol Prostaglandin-E1 Methyl Ester Patchouli Alcohol (-)-Vindoline Biotin Annotinine Silphiperfolene Dodecahedrane Eremophilone Vernolepin and Vernomenin Albolic Acid and Ceroplastol-II Lupeol (+)-Epoxydictymene Cyclocolorenone Modhephene Griseofulvin Dehydrotubifoline and Akuammicine Allopumiliotoxin-267A β-Vetivone Laurenene Streptazolin Cantharidin Quadrone Regiochemical Problems: Δ1-Tetrahydrocannabinol Resistomycin (-)-Hapalindole-G Estradiol Confertin Coriolin Phyllanthocin Chlorophyll-a Taxol Retigeranic Acid-A Index Readership: Organic chemists -->Keywords: ; --> Updated contents, pp & pub date on 30/7/96 -->

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