摘要：

The syntheses of bicyclo[2.1.1]hexane, 1-chlorobicyclo[2.1.1]hexane and some of their derivatives are described. A convenient method of decarboxylating aliphatic acids via the decomposition of the t-butyl peresters in cymene has been developed. The reactions of bicyclo[2.1.1]hexanol-5 leading to unrearranged, partially rearranged or completely rearranged products depending on the reagents present are described.

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