摘要：

lSSN 0300-9246 J C DTB I ( 1 0) 2485-2800 ( 1 991 )JOURNAL OF THE CH EM I CAL SOCIETYDalton TransactionsInorganic Chemistryincluding bioinorganic, organometallic and solid-state chemistryCONTENTS2485 New bis(ferrocenecarbony1)- and bis(ferroceny1)-appended diazatetrathia mixed-donor macrocyclic ligands and theircopper-(II) and -(I) complexes Paul D. Beer, Jayne E. Nation, Sean L. W. McWhinnie, Mary E. Harman, Michael B.Hursthouse, Mark I. Ogden and Allan H. WhiteMacrocyclic ligand ring size effects. Part 2. Synthetic, structural and electrochemical studies of the interaction of Ni“ with14-membered tetraaza macrocycles containing fused dibenzo substituents Kenneth R. Adam, Michael Antolovich, LarryG. Brigden, Anthony J. Leong, Leonard F. Lindoy, Philip J.Baillie, Daljit K. Uppal, Mary McPartlin, Bhavini Shah, DavideProserpio, Luigi Fabbrizzi and Peter A. TaskerInsertion of mercury into iron-halogen bonds. X-Ray structure of [(p-MeC6H4NC)SFe-+Hg12] Silverio Coco, PabloEspinet, Fernando Mayor and Xavier SolansSynthesis and structures of tetranuclear 2-(dimethy1amino)ethanethiolato complexes of zinc, cadmium and mercuryinvolving both primary and secondary metal-halogen bonding Isidre Casals, Pilar Gonziilez-Duarte, William Clegg,Concha Foces-Foces, FClix Herniindez Cano, Martin Martinez-Ripoll, Montserrat G6mez and Xavier SolansReactions of the hydridethiolate complexes [MH(SC6H,R3-2,4,6)3(PMe2Ph)2] (M = Mo or W, R = Me or Pri): X-raycrystal structures of [M(SC,H,Pri,-2,4,6),(CO),(PMe,Ph),] (M = Mo or W) Timothy E.Burrow, Alan J. Lough,Robert H. Morris, Adrian Hills, David L. Hughes, Janette D. Lane and Raymond L. RichardsSynthesis, characterization and stereochemistry of condensation products between (1 R)-3-hydroxymethylenebornane-2-thione and diamines and their metal complexes Luigi Casella, Michele Gullotti, Roberto Pagliarin and Massimo SistiComplex formation between squarate (C4042 -) and Cu”L [L = 2,2’-bipyridyl, 2,2’ : 6’,2”-terpyridyl or bis(2-pyridyl-carbony1)amide anion (bpca)] in dimethyl sulphoxide solution. Crystal structure of [Cu,(bp~a)~(H~O),(C~0~)] IsabelCastro, Juan Faus, Miguel Julve, Yves Journaux and Jorunn SlettenCopper complexes of l,l-di(2-pyridyl)ethyl methyl ether: X-ray crystal structures and reactions with dioxygen SumitBhaduri, Niteen Y.Sapre and Peter G. JonesSynthesis, characterization, luminescence properties, and electrochemical behaviour of ruthenium(i1) complexes with twonew bi- and tri-dentate 2-pyridylquinoline ligands Sebastiano Campagna, Antonino Mamo and John K. StilleElectrochemical and Mossbauer studies on iron@) complexes of a new series of entwining ligands: stabilization of uni- andzero-valent oxidation states Md. Athar Masood, Ranga Jagannathan and Panthappally S. ZachariasMolecular organization and dynamic behaviour of arene cluster complexes in the solid state. Crystal structures of[Os,H,(CO), ,,(‘q6-C6H~Me)], [Os4H2(CO) lo(~6-C6H4Me2)] and [Ru,C(CO) 14(~6-C6H3Me3-l ,3,5)] Dario Braga,Fabrizia Grepioni, Brian F. G. Johnson, Hong Chen and Jack LewisSynthesis of heteronuclear gold-rhodium cluster compounds and structural characterisation of [Rh(CNC,H,),-( A u P P ~ ~ ) ~ ] ~ + , [Rh(CNC8H9),(A~PPh3),(AuCl),]+ and [Rh(CO),(AuPPh3)-,12+ Simon G.Bott, Holm Fleischer,Mike Leach, D. Michael P. Mingos, Harry Powell, David J. Watkin and Michael J. WatsonSynthesis and structural characterization of gold-(I), -(III) and silver(1) complexes of the ylide ligand Ph,P=CHC(O)NMe,.Crystal structure of [(AUPP~~)~(~-C(PP~,)C(O)NM~~)]C~~~ J o d Vicente, Maria-Teresa Chicote, Maria-CristinaLagunas and Peter G. Jones2493250325 1 1251925272533253925452553255925692579CONTENTS25852595260 1260726152619262526332639264326492657266926772685269 327032707271 12717272327292735The chemistry of uranium.Part 42. Cationic uranium(1v) complexes UX,L,Y, (X = C1, Br or I; Y = ClO, or BPh,; L =bulky strong neutral 0-donor ligand) and [U(ClO,),(OAsPh,),]: crystal structures of [UX,L,][BPh,], (L =tris(pyrro1idine-1-y1)phosphine oxide, X = Br or I) Jan G. H. du Preez, Leon GOUW

展开