Identification of α-Chloro-2,2′,4,4′,6,6′-Hexanitrobibenzyl as an Impurity in Hexanitrostilbene
摘要：
The final intermediate in the Shipp synthesis of 2,2,4,4,6,6-hexanitrostilbene (HNS) from TNT, ±-chloro-2,2,4,4,6,6-hexanitrobibenzyl, has been extracted and characterized by nuclear magnetic resonance (NMR) spectroscopy, chlorine elemental analysis, and high-performance liquid chromatography (HPLC). It has also been shown that digestion in NMP of HNS containing ±-chlorohexanitrobibenzyl generates another chlorine-containing by-product, 2-chloro-2,4,4,6,6-pentanitrostilbene. This too has been characterized by NMR spectroscopy, chlorine elemental analysis, and HPLC.
展开
关键词：
α-chloro-2,2′,4,4′,6,6′-hexanitrobibenzyl 2,2′,4,4′,6,6′-hexanitrostilbene (HNS) 2-chloro-2′,4,4′,6,6′-pentanitrostilbene
DOI：
10.1080/07370650902961258
被引量：
年份：
2010
相似文献
参考文献
引证文献
辅助模式
引用
文献可以批量引用啦~
欢迎点我试用！
