Catalysis ofO-(para-nitrophenyl)O,O-dimethyl thiophosphate decomposition by chromonic mesophases based on polymerized ionic amphiphiles
摘要:
The formation of a nematic chromonic mesophase in aqueous solutions of quaternized poly(ethylene imine) has been found using polythermal polarization microscopy. The reaction kinetics of O-para-nitro-phenyl) O,O-dimethyl thiophosphate hydrolysis has been studied by spectrophotornetry, and a comparative analysis of the effects of lyotropic liquid crystals constructed as hexagonal and chromonic mesophases on this kinetics has been performed. It has been found that the hydrolysis of the substrate in a nematic chromonic mesophase is accelerated due to the concentration ofthe reactants.
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DOI:
10.1134/s0023158406010010
年份:
2006


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