Diels-Alder reactions in chloroaluminate ionic liquids: acceleration and selectivity enhancement
摘要：
The utility of room temperature chloroaluminate ionic liquids as solvent and catalyst for the synthetically important Diels-Alder reaction was studied. The AlCl3-1-ethyl-3-methyl-1H-imidazolium chloride medium proved to be ideally suited for Diels-Alder reactions. Endo selectivity and rate enhancement were observed for the cyclopentadiene/methyl acrylate Diels-Alder reaction.
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DOI：
10.1016/S0040-4039(99)00249-X
被引量：
年份：
1999
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