Synthesis of Functionalized Organotrifluoroborates via Halomethyltrifluoroborates

来自 ACS

阅读量:

20

作者:

GaryA.MolanderJungyeobHam

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摘要:

Potassium bromo- and iodomethyltrifluoroborates have been prepared via in situ reaction of n-BuLi with dibromo- and diiodomethane, respectively, in the presence of trialkyl borates, followed by treatment with KHF2. Moreover, a new synthetic method for the preparation of potassium organotrifluoroborates through nucleophilic substitution of the halide in these potassium halomethyltrifluoroborates is described.

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DOI:

10.1021/ol060375a

年份:

2006

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