Synthesis of Functionalized Organotrifluoroborates via Halomethyltrifluoroborates
摘要:
Potassium bromo- and iodomethyltrifluoroborates have been prepared via in situ reaction of n-BuLi with dibromo- and diiodomethane, respectively, in the presence of trialkyl borates, followed by treatment with KHF2. Moreover, a new synthetic method for the preparation of potassium organotrifluoroborates through nucleophilic substitution of the halide in these potassium halomethyltrifluoroborates is described.
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DOI:
10.1021/ol060375a
年份:
2006
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