Hybrid magnetic solids of radical-substituted heteroaromatic compounds with metal halides
摘要：
Complexes of manganese(II), cobalt(II), nickel(II), and copper(II) chlorides with 5-pyrimidinyl nitronyl nitroxide (5PMNN) and pyrazinyl nitronyl nitroxide (PZNN) were synthesized. Ni- and CoCl 2·(5PMNN) 2 showed magnetic phase transitions at 5.8 and 2.3 K, respectively, and spin–flip behavior below the transition temperatures. X-ray crystal structure analyses revealed that Mn- and CoCl 2·(PZNN) 2 were mononuclear.
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DOI：
10.1016/S0379-6779(02)00360-0
被引量：
年份：
2003
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