摘要：

Chiral Lewis acid-catalyzed enantioselective nitrooxylation of cyclic and acyclicβ-keto amides/esters with hypervalent iodine(III)reagents is reported.A number ofα-nitrooxy-β-keto amides/esters were obtained with good yields and high enantioselectivities by using bench-stable nitratobenziodoxole under mild conditions.

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