PEG-supported dipyridyl ligand for palladium-catalyzed Suzuki and Suzuki-type reactions in PEG and aqueous media
摘要：
An air- and water-stable PEG-supported bidentate nitrogen ligand is prepared and its applications in the palladium-catalyzed Suzuki reaction of aryl halides with arylboronic acids in PEG and Suzuki-type reaction of aryl halides with sodium tetraphenylborate in aqueous media are reported. The homogeneous catalyst system is environmentally friendly and offers the advantages of high activity, reusability and easy separation.
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关键词：
Suzuki reaction ligand reusability PEG CROSS-COUPLING REACTIONS SUPERCRITICAL CARBON-DIOXIDE TEMPERATURE IONIC LIQUIDS FRIEDEL-CRAFTS REACTIONS ARYL CHLORIDES ARYLBORONIC ACIDS POLY(ETHYLENE GLYCOL) ORGANIC-SYNTHESIS SOLUBLE POLYMERS HOMOGENEOUS CATALYSTS
DOI：
10.1055/s-2006-951488
年份：
2006
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