Structure-Directing Effects in the Supramolecular Intercluster Compound [Au 9 (PPh 3 ) 8 ] 2 [V 10 O 28 H 3 ] 2 : Long-Range versus Short-Range Bonding Interactions
摘要：
Although being composed of trivalent ions, the crystal structure ofthe supramolecular intercluster compound [Au<sub>9</sub>(PPh<sub>3</sub>)<sub>8</sub>]<sub>2</sub>[V<sub>10</sub>O<sub>28</sub>H<sub>3</sub>]<sub>2</sub>is dominated by short-range intermolecular interactions, i.e.,hydrogen bonds, and C−H/π interactions, avoiding a simple AB-type packing. Although being composed of trivalent ions, the crystal structure of the supramolecular intercluster compound [Au<sub>9</sub>(PPh<sub>3</sub>)<sub>8</sub>]<sub>2</sub>[V<sub>10</sub>O<sub>28</sub>H<sub>3</sub>]<sub>2</sub> is dominated by short-range intermolecular interactions, i.e., hydrogen bonds and C−H/π interactions, avoiding a simple AB-type packing.
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DOI：
10.1021/ic700434x
年份：
2007
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