Boron Clusters: Do They Receive the Deserved Interest?
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22
摘要：
New applications in which the carborane and metallacarborane species play a crucial role have been recently developed. In these applications, clusters display many particular characteristics that do not find parallel in their organic counterparts. The o-carborane can modulate the C...C distances depending on the substituents bonded to the cluster carbon atom and can lead to the formation of uncommon halogenophosphane charge-transfer "spoke" complexes with iodine due to their electron-withdrawing capacity. Besides, metallacarboranes have been used as doping agents in organic conducting polymers and as catalysts in Kharasch reactions.
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DOI：
10.1002/chin.200448275
被引量：
年份：
2004
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