ChemInform Abstract: Asymmetric Aldol Reaction of α‐Keto Esters with Isocyanoacetate and Isocyanoacetamide Catalyzed by a Chiral Ferrocenylphosphine/Gold(I) Complex.
摘要：
Biacetyl (Ia) and the α-keto esters (Ib) - (Id) react with N,N-dimethylisocyanoacetamide or methyl isocyanoacetate (II) in the presence of a diphenylphosphinoferrocene/gold(I) catalyst system to form the oxazolidines (III) as the main products, together with the diastereomers (IV).
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关键词：
oxazole derivatives stereochemistry (general, optical resolution cleavage reactions, decomposition reactions, pyrolysis carboxylic acid esters (acyclic compounds carboxylic amides (benzene compounds
DOI：
10.1002/chin.199014166
被引量：
年份：
1990
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