Palladium-Catalyzed Oxidative Borylation of Allylic C–H Bonds in Alkenes
摘要：
This communication describes an efficient palladium pincer complex-catalyzed allylic C-H borylation of alkenes. The transformation exhibits high regio- and stereoselectivity with a variety of linear alkenes. A synthetically useful feature of this allylic C-H borylation method is that all allyl-Bpin products can be isolated in usually high yields. Preliminary mechanistic studies indicate that this C-H borylation reaction proceeds via Pd(IV) pincer complex intermediates.
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DOI：
10.1021/acs.orglett.7b03296
年份：
2017
Elsevier
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