Nitrogen- and Sulfur-Containing Energetic Compounds. 64 Years of Fascinating Chemistry*
摘要：
This essay details the author's work with high-energy molecules based on sulfur or nitrogen, or both, which started with amateur rocket propellants like zinc dust and sulfur followed by experiments with the highly sensitive compounds nitrogen trichloride and fulminating gold. Research on the inorganic and organic fulminates and the isomeric cyanates led to detailed investigations of reactive intermediates generated by flash vacuum pyrolysis or photolysis, in particular nitrenes and carbenes derived from azides, diazo compounds, triazoles, and tetrazoles and characterized in low temperature matrices.
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DOI：
10.1071/CH19263
年份：
2019
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来源期刊
Australian Journal of Chemistry
2019/09/09
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