Effect of 2-Butene CislTrans Isomers in the Metathesis of Ethylene and 2-Butene Over WOs/SiO2 Catalysts
摘要:
Pure 2 %raws-2-butenendheixturef 1 %is-and 1 %rans-2-bvXene weresedseedoeact with ethylene inetathesiseaction inrdero produce propyleneotudyhe effectfeedn WO3/SiO2atalysts with variousungstenxide loadings (5, 7, 9,nd 11 wt%), which were preparedy incipient wetness impregnation.heseatalysts wereharacterizedy X-ray diffraction, nitrogendsorption (BET),canning electronicroscopy, energy dispersive X-raypectroscopy, ion-exchangeitration,T-Raman,mmoniaemperature programmed desorption (NH3-TPD)ndeactant-TPD.tighungstenxide loading, whenheixturefis-andrans-2-butene wassedsheeactioneedheonversionf 2-butene was lowerhan when pureran.s-2-butene wassed.owever,he effectfw-2-butene isomernheonversionf 2-butene was less pronouncedt lowungstenxide loading.he dispersionfungsten was keyactoro improvehectivityfheungstenatalysts whenheixturefis-andrans-2-butene wassedseedoretathesiseaction.
展开
DOI:
10.1007/sl0562-014-1230-8
年份:
2014

通过文献互助平台发起求助,成功后即可免费获取论文全文。
相似文献
参考文献
引证文献
来源期刊
辅助模式
引用
文献可以批量引用啦~
欢迎点我试用!