Field desorption mass spectrometry of natural products—II

阅读量:

73

作者:

HR SchultenT KomoriT Kawasaki

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摘要:

Field desorption mass spectra of underivatized oligoglycosides of spirostanol and its congeners and of hederagenin revealed the molecular weight and structural information. The basic predominance of the formation of stable ions of highly polar natural products (with 5–17 free OH functions) is clearly demonstrated. After the extraction and purification procedure from plant material the samples contained inorganic salts in concentrations between 0.01 and 0.1%. These salt impurities, mostly alkali halides, strongly promoted the attachment of alkali cations to the intact molecules and their fragments. The ions produced gave analytical information not only for the confirmation of the molecular weight but also for the identity of the aglycone and, to some extent, for the sequence of the sugars in the oligoglycosides. All spectra were recorded on photoplates at a resolution of better than 15000 and enabled the evaluation of the elemental composition of the ions generated. The drawbacks and merits of integrating ion recording using the photoplate for FD investigations of highly polar substances are discussed.

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DOI:

10.1016/0040-4020(77)80085-9

被引量:

126

年份:

1977

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来源期刊

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2010
被引量:18

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