Syntheses and magnetic properties of three Mn(II) coordination polymers based on a tripodal flexible ligand
摘要：
The solvothermal reaction of Mn(ii) and tri(2-carboxyethyl)isocyanurate (H3tci) with or without the presence of 1,2-bis(4-pyridyl)ethylene in different solvents leads to the generation of three novel Mn(ii) coordination polymers, namely, Mn3(tci)2(DMF)2(H2O)2(1), [Mn3(tci)2(DMA)4]·2DMA (2) and [Mn(Htci)(bpe)0.5]·H2O (3).1features a 3D porous coordination polymer constructed by {Mn–(μ2–O)–Mn}nchains linked by the flexible arms of tci ligands.2features a 2D CdI2topological layer based on trinuclear Mn(ii) clusters as nodes.3is a 3D pillar-layered structure. The magnetic properties of these complexes have also been reported.
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DOI：
10.1039/c1ce06213a
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年份：
2012
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来源期刊
CrystEngComm
20120206
引用走势
2013
被引量：18
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