Chiral Salen?Aluminum Complex as a Catalyst for Enantioselective α-Addition of Isocyanides to Aldehydes:? Asymmetric Synthesis of 2-(1-Hydroxyalkyl)-5-aminooxazoles
摘要：
In the presence of a catalytic amount of (salen)Al(III)Cl complex (<bold>4e</bold>), reaction between α-isocyanoacetamides (<bold>1</bold>) and aldehydes (<bold>2</bold>) affordedthe corresponding 5-aminooxazoles (<bold>3</bold>) in good yields and enantioselectivity.
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关键词：
AMINO-ACID-DERIVATIVES MULTICOMPONENT DOMINO PROCESS LEWIS-ACID PASSERINI REACTION ALDOL REACTION FERROCENYLPHOSPHINE-GOLD(I) COMPLEX CONJUGATE ADDITION 3+2 CYCLOADDITION ISOCYANOACETATE ISONITRILE
DOI：
10.1021/ol7014658
年份：
2007
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