Synthesis of carbazoles by dehydro Diels-Alder reactions of ynamides

来自 万方

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13

作者:

ADLC Martinez-Esperon

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摘要:

A new approach to carbazoles and benzarmulated carbazoles by means of intramolecular dehydro Diels-Alder of ynarnides is reported. N-(o-Ethynvl)aryl ynamides and N-(o-ethynyl) arylynamides were prepared in a few steps starting from o-iodoaniline. Thermal cycloaddition of N-(o-ethynyl)aryl ynamides and N-(o-ethynyl) arylynamides affords carbazoles and benzarmulated and heteroarmulated carbazoles in moderate-to-good yields. (c) 2008 Elsevier Ltd. All rights reserved.

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年份:

2008

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