Synthesis of carbazoles by dehydro Diels-Alder reactions of ynamides
摘要:
A new approach to carbazoles and benzarmulated carbazoles by means of intramolecular dehydro Diels-Alder of ynarnides is reported. N-(o-Ethynvl)aryl ynamides and N-(o-ethynyl) arylynamides were prepared in a few steps starting from o-iodoaniline. Thermal cycloaddition of N-(o-ethynyl)aryl ynamides and N-(o-ethynyl) arylynamides affords carbazoles and benzarmulated and heteroarmulated carbazoles in moderate-to-good yields. (c) 2008 Elsevier Ltd. All rights reserved.
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关键词:
DOUBLE N-ARYLATION 4+2 CYCLOADDITION REACTIONS THIN-FILM TRANSISTORS CYCLIC ALLENES HIGHLY EFFICIENT CONJUGATED ENYNES PRIMARY AMINES ELLIPTICINE DERIVATIVES CYCLIZATION
年份:
2008
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