Hydrocarboxylation of terminal alkenes in supercritical carbon dioxide using perfluorinated surfactants
摘要：
High selectivity in acids is obtained in the first example of hydrocarboxylation of 1-octene in supercritical carbon dioxide using a Pd/P(4-C6H4-CF3)3 catalyst system and a perfluorinated surfactant.
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关键词：
PALLADIUM-CATALYZED HYDROCARBOXYLATION ENANTIOSELECTIVE HYDROGENATION WATER HYDROFORMYLATION COMPLEXES MICROEMULSIONS MEDIA HYDROXYCARBONYLATION CARBONYLATION ENVIRONMENT
DOI：
10.1039/B603370A
年份：
2006
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