First total synthesis of heterocurvistone
摘要：
The sesquiterpene ketone (+/-)-heterocurvistone was synthesized in eight steps and 12% overall yield from known methyl R-(+)-3-(4-methyl-3-cyclohexen-1-yl)-3-butenoate, readily available from R-(+)-limonene. The key synthetic step is an oxymercuration-induced cyclization. (C) 2003 Published by Elsevier Science Ltd. [References: 18]
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关键词：
Heterocurvistone Isoheterocurvistone Heterocurvistol Isoheterocurvistol Sesquicineole derivatives Synthesis Terpene derivatives Hydroperoxide Epoxidations Alcohols
年份：
2003
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