Chiral salen-aluminum complex as a catalyst for enantioselective alpha-addition of isocyanides to aldehydes: Asymmetric synthesis of 2-(1-hydroxyalkyl)-5-aminooxazoles
摘要：
In the presence of a catalytic amount of (salen)Al(III)Cl complex (4e), reaction between alpha-isocyanoacetamides (1) and aldehydes (2) afforded the corresponding 5-aminooxazoles (3) in good yields and enantioselectivity.
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关键词：
AMINO-ACID-DERIVATIVES MULTICOMPONENT DOMINO PROCESS LEWIS-ACID PASSERINI REACTION ALDOL REACTION FERROCENYLPHOSPHINE-GOLD(I) COMPLEX CONJUGATE ADDITION 3+2 CYCLOADDITION ISOCYANOACETATE ISONITRILE
年份：
2007
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