ASYMMETRIC COPPER-CATALYSED ALKENE CYCLOPROPANATION AND AZIRIDINATION USING TARTRATE-DERIVED BIS-OXAZOLINE LIGANDS
摘要:
The enantioselective cyclopropanation and aziridination of styrene using chiral tartrate-derived bis-oxazoline ligands 1, 6, and 7 is reported. The effects of variation of the size of the oxazoline substituent (R(1)) and the size of the diazoacetate ester substituent (R(2)) on the level and sense of enantioselection is described. Copyright (C) 1996 Elsevier Science Ltd [References: 11]
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年份:
1996
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