Nonlinear Effects Involving Two Competing Pseudo-Enantiomeric Catalysts: Example in Asymmetric Dihydroxylation of Olefins.

作者:

S ZhangC GirardH Kagan

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摘要:

Asymmetric catalysis in the case of a mixture of pseudo-enantiomeric ligands has been studied in the Sharpless asymmetric dihydroxylation of bis-( ortho -bromo)stilbene. Nonlinear behaviours were observed in this situation, one spectacular case being evidenced [(DHQD) 2 -PHAL / PCB-DHQ mixtures].

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DOI:

10.1002/CHIN.199613037

年份:

1996

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来源期刊

ChemInform
1996-03-26

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