Nonlinear Effects Involving Two Competing Pseudo-Enantiomeric Catalysts: Example in Asymmetric Dihydroxylation of Olefins.
摘要:
Asymmetric catalysis in the case of a mixture of pseudo-enantiomeric ligands has been studied in the Sharpless asymmetric dihydroxylation of bis-( ortho -bromo)stilbene. Nonlinear behaviours were observed in this situation, one spectacular case being evidenced [(DHQD) 2 -PHAL / PCB-DHQ mixtures].
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DOI:
10.1002/CHIN.199613037
年份:
1996
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来源期刊
ChemInform
1996-03-26
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