摘要：

PurposeThe purpose of this paper is to synthesize and characterize nano-ceramic blue pigment Co0.5Zn0.5Al2O4 via polyacrylamide gel method. Generally, the high cost and the environmental toxicity of cobalt aluminate pigments lead them to become less common and cause problems in production process. To significantly reduce this problem, it is required to reduce the cobalt in the pigment and replace the cobalt with some amounts of zinc in the structure.Design/methodology/approachIn this paper, calcination temperature and its effects on phase specification and color properties of final product were investigated. The powders were studied by using XRD, FESEM, TG/DTA, FTIR, UV-Vis and colorimetric in CIELab space, in which the calcination temperatures were set to 600°C, 800°C and 1,000°C, and the inert atmosphere was air.FindingsAccording to the XRD patterns, single-phase spinel structure with a good crystallinity was formed even in the low temperature. The infrared spectra displayed vibrations at about 500, 560 and 680cm1, which were ascribed to the spinel structure. FESEM images showed nanoscale particles with an average size of 32nm. Regarding the Co2+ spin transitions in tetrahedral sites, the UV-Vis spectra presented three bands at 552, 598 and 628nm.Practical implicationsThe colorimetric data indicated the formation of blue pigments corresponding to negative values of b*. The color of pigments was affected by calcination temperature.Originality/valueThe characterization analysis shows that a blue pigment has been obtained in this research. Different degrees of blue color were obtained at different calcination temperatures.

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